Mineralogy and origin of rhizoliths on the margins of saline,alkaline Lake Bogoria,Kenya Rift Valley     

Richard Alastair Owen  Richard Bernhart Owen  Robin W. Renaut  Jennifer J. Scott  Brian Jones  Gail M. Ashley 《Sedimentary Geology》2008,203(1-2):143-163

A wide range of rhizoliths occurs around the margins of Lake Bogoria, Kenya. These include root casts, moulds, tubules, rhizocretions, and permineralised root systems. These rhizoliths are variably composed of opaline silica, calcite, zeolites (mainly analcime), fluorite, and possibly fluorapatite, either alone or in combinations. Some rhizoliths are infilled moulds with detrital silicate grains. Most rhizoliths are in situ, showing both vertical and horizontal orientations. Reworked rhizoliths have been concentrated locally to form dense rhizolites.Hot-spring fluids, concentrated by evapotranspiration and capillary evaporation, have provided most of the silica for the permineralisation of the plant tissues. Precipitation involved the growth of silica nanospheres and microspheres that coalesced into homogeneous masses. Calcite rhizoliths formed following evaporative concentration, evapotranspiration, and (or) CO₂ degassing of Ca-bearing runoff water that infiltrated the sediment, or by mixing of runoff with saline, alkaline groundwater. Fluorite precipitated in areas where mixing of hot-spring and meteoric waters occurred, or possibly where hot-spring fluids came into contact with pre-existing calcite. Zeolitic rhizoliths formed during a prolonged period of aridity, when capillary rise and evaporative pumping brought saline, alkaline waters into contact with detrital silicate minerals around roots.  相似文献   

Electrochemical study of hydrothermal and sedimentary pyrite dissolution     

Ran Liu  Amy L. Wolfe  David A. Dzombak  Colin P. Horwitz  Brian W. Stewart  Rosemary C. Capo 《Applied Geochemistry》2008

The dissolution of pyrite is of interest in the formation of acid mine drainage and is a complex electrochemical process. Being able to measure the rate of dissolution of particular pyrite samples under particular conditions is important for describing and predicting rates of AMD generation. Electrochemical techniques offer the promise of performing such measurements rapidly and with small samples. The oxidation of pyrite and the reduction of Fe³⁺ ions and/or O₂ half reactions involved in the pyrite dissolution process were investigated by cyclic voltammetry and steady-state voltammetry using three pyrite materials formed in both sedimentary and hydrothermal environments. For each sample, two kinds of pyrite working electrodes (conventional constructed compact solid electrode, and carbon paste electrode constructed from fine-grained pyrite particles) were employed. Results indicated that for both the hydrothermal and sedimentary pyrite samples the oxidation and reduction half reactions involved in dissolution were governed by charge transfer processes, suggesting that hydrothermal and sedimentary pyrites obey the same dissolution mechanism despite their different formation mechanisms. In addition, the results showed that it is feasible to use a C paste electrode constructed from fine-grained or powdered pyrite to study the pyrite dissolution process electrochemically and to derive approximate rate expressions from the electrochemical data.  相似文献   

Assessment of lightning-related fatality and injury risk in Canada   总被引：2，自引：0，他引：2  

Brian Mills  Dan Unrau  Carla Parkinson  Brenda Jones  Jennifer Yessis  Kelsey Spring  Laurel Pentelow 《Natural Hazards》2008,47(2):157-183

This article summarizes research completed to assess the risk of lightning-related injuries and fatalities in Canada. Although lightning mortality has declined significantly over the past century, it remains a common meteorological hazard that regularly kills and injures. Based on an analysis of media reports, vital statistics, hospital admission and emergency room visit records, and fire loss data, the authors estimate that on average about 9–10 lightning-related deaths and 92–164 injuries occur each year in Canada. The distribution of casualties reflects current provincial population and cloud-to-ground lightning densities. Consistent with similar studies in other developed nations, most lightning-related fatalities and injuries in Canada occur during the June-August summer season, coincident with peak lightning, and during the Thursday-Saturday period, most likely related to higher rates of participation in outdoor activities. The majority of victims are male, less than 46 years old, and engaged in outdoor recreational activities when injured or killed in a lightning incident. Media reports used in the study were found to underestimate both lightning mortality (36%) and morbidity (20–600%).

Brian MillsEmail:

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Comparison of dissolution under oxic acid drainage conditions for eight sedimentary and hydrothermal pyrite samples   总被引：1，自引：0，他引：1  

Ran Liu  Amy L. Wolfe  David A. Dzombak  Brian W. Stewart  Rosemary C. Capo 《Environmental Geology》2008,56(1):171-182

The abiotic oxidative dissolution behaviors of eight natural pyrite samples, five sedimentary and three hydrothermal, from various geological environments were compared under oxic conditions at pH 3 and 6 in a highly controlled batch reactor dissolution system. The three sedimentary pyrite samples associated with coal had greater specific surface areas and also exhibited greater apparent dissolution rates and extent than the other two sedimentary and three hydrothermal samples under both pH conditions. However, after normalizing for surface area, the dissolution rate constants for the different pyrite samples were similar; the greatest difference was between the two non-coal sedimentary pyrite samples. Pyrite morphology and the presence of trace metals could contribute to the differences in dissolution behavior as reflected in the normalized dissolution rates. The sulfur:iron ratio observed in the aqueous solution at pH 3 increased with time, but was always less than 2.0 (predicted from the stoichiometry of dissolution) for all the pyrite samples during the 24-h experimental duration. This can be explained by the disproportionation dissociation of thiosulfate, an initial product of pyrite dissolution, to elemental sulfur and sulfate which does not occur in a 1:1 ratio. The results of this work indicate the importance of extracting and using the specific pyrite(s) relevant to particular mining areas in order to understand pyrite dissolution rates and the influence of environmental conditions on those rates.  相似文献   

Large-scale moraine deformation at the Athabasca Glacier,Jasper National Park,Alberta, Canada     

Chris H. Hugenholtz  Brian J. Moorman  John Barlow  Pablo A. Wainstein 《Landslides》2008,5(3):251-260

In this paper the development of a large-scale gravitational deformation involving the eastern lateral moraine of the Athabasca Glacier in Jasper National Park, Alberta, Canada, is described. Interpretation and analysis of sequential aerial photographs indicates that a 540-m-wide segment of the eastern lateral moraine began to deform in the early 1950s; however, significant movement only began in the late 1960s. Since then, the moraine has undergone progressive gravitational deformation leading to a network of fractures, bulging, and the development of a large gap in the moraine crest. Geographic information system analysis of topographic changes between 1967 and 2006 indicates that the displaced volume of the moraine is approximately 9.0 × 10⁵ m³. In the last 39 years, the moraine crest has displaced 55 m (1.4 m yr⁻¹) down towards the glacier. The development of slope instability is linked to a combination of debuttressing from recent glacier recession, deformation of the moraine, as well as the movement of a large, mobile, debris-mantled slope impinging the upslope margin of the lateral moraine. This case study illustrates the importance of glacial conditioning and local geomorphological factors in creating conditions for large-scale moraine instability in recently deglacierized alpine basins.  相似文献   

Open Bays as Nurseries for Louisiana Brown Shrimp     

Brian Fry 《Estuaries and Coasts》2008,31(4):776-789

Previous studies of Louisiana estuaries have indicated a central role of Spartina alterniflora marshes in supporting production of the commercially important brown shrimp, Farfantepenaeus aztecus. Brown shrimp are an estuarine-dependent species and spend one to three springtime months in estuaries as small juveniles, with highest shrimp densities found at marsh edges. Later estuarine and offshore production of brown shrimp is correlated both with marsh area and with abundance of smaller juveniles found in unvegetated open bays near marshes. This paper investigates the idea that open bays are an additional important nursery habitat for Louisiana brown shrimp, with bays possibly supporting the bulk of shrimp populations even while shrimp densities expressed on a square meter basis are lower in the bays. To assay possible differences in shrimp abundances and residency in marsh ponds vs. adjacent open bays, springtime field work was conducted in 2004–2006 near the Louisiana University Marine Consortium Laboratory at Cocodrie, Louisiana. Seine surveys showed similar-sized shrimp were present in marsh ponds (<20 m in diameter) and an adjacent open bay (<1 m deep, 2 km in diameter) and that shrimp were twice as dense in the marsh ponds. Natural C, N, and S isotope tags provided distinctive labeling of shrimp from marsh ponds versus bays; shrimp residency appeared high in both areas with <10% of shrimp present as immigrants from other areas. Widely spaced collections from several Louisiana bay systems and also Galveston Bay, Texas showed that the S isotope tags provided the most general tags for marsh origins, with low S isotope values of 1–9‰ in shrimp muscle tissue consistently indicating marsh origins. Importance of marshes for brown shrimp production across Terrebonne and Barataria Bays, Louisiana was evaluated with S isotopes using spring 2005 collections. Results showed that marshes supported about 1/3 of total shrimp production; 2/3 of Louisiana brown estuarine shrimp production may depend on the three to four times more extensive open bays. Given these results, coastal restoration efforts in Louisiana might focus on measures such as barrier island conservation and restoration that protect both bays and marshes, rather than focusing on measures that specifically target marshes and neglect open bays.  相似文献   

Real-time hybrid simulation for structural control performance assessment   总被引：2，自引：2，他引：0  

Juan E Carrion  BF Spencer Jr  Brian M Phillips 《地震工程与工程振动(英文版)》2009,8(4):481-492

Real-time hybrid simulation is an attractive method to evaluate the response of structures under earthquake loads.The method is a variation of the pseudodynamic testing technique in which the experiment is executed in real time,thus allowing investigation of structural systems with rate-dependent components.Real-time hybrid simulation is challenging because it requires performance of all calculations,application of displacements,and acquisition of measured forces,within a very small increment of time.Furthe...  相似文献   

Macro- and Micro-Purge Soil-Gas Sampling Methods for the Collection of Contaminant Vapors     

Brian A. Schumacher  John H. Zimmerman  Christopher R. Sibert  Katrina E. Varner  Lee A. Riddick 《Ground Water Monitoring & Remediation》2009,29(1):138-143

Purging influence on soil‐gas concentrations for volatile organic compounds (VOCs), as affected by sampling tube inner diameter and sampling depth (i.e., system volume) for temporary probes in fine‐grained soils, was evaluated at three different field sites. A macro‐purge sampling system consisted of a standard, hollow, 3.2‐cm outer diameter (OD) drive probe with a retractable sampling point attached to an appropriate length of 0.48‐cm inner diameter (ID) Teflon^® tubing. The macro‐purge sampling system had a purge system volume of 24.5 mL at a 1‐m depth. In contrast, the micro‐purge sampling systems were slightly different between the field sites and consisted of a 1.27‐cm OD drive rod with a 0.10‐cm ID stainless steel tube or a 3.2‐cm OD drive rod with a 0.0254‐cm inner diameter stainless steel tubing resulting in purge system volumes of 1.2 and 7.05 mL at 1‐m depths, respectively. At each site and location within the site, with a few exceptions, the same contaminants were identified in the same relative order of abundances indicating the sampling of the same general soil atmosphere. However, marked differences in VOC concentrations were identified between the sampling systems, with micro‐purge samples having up to 27 times greater concentrations than their corresponding macro‐purge samples. The higher concentrations are the result of a minimal disturbance of the ambient soil atmosphere during purging. The minimal soil‐gas atmospheric disturbance of the micro‐purge sampling system allowed for the collection of a sample that is more representative of the soil atmosphere surrounding the sampling point. That is, a sample that does not contain an atmosphere that has migrated from distance through the geologic material or from the surface in response to the vacuum induced during purging soil‐gas concentrations. It is thus recommended that when soil‐gas sampling is conducted using temporary probes in fine‐grained soils, the sampling system use the smallest practical ID soil‐gas tubing and minimize purge volume to obtain the soil‐gas sample with minimal risk of leakage so that proper decisions, based on more representative soil‐gas concentrations, about the site can be made.  相似文献   

Exploring the nature of non-Fickian transport in laboratory experiments     

Brian Berkowitz  Harvey Scher 《Advances in water resources》2009

Observations of non-Fickian transport in sandbox experiments [Levy M, Berkowitz B. Measurement and analysis of non-Fickian dispersion in heterogeneous porous media. J Contam Hydrol 2003;64:203–26] were analyzed previously using a power law tail ψ(t) ∼ t^−1−β with 0 < β < 2 for the spectrum of transition times comprising a tracer plume migration. For each sandbox medium a choice of β resulted in an excellent fit to the breakthrough curve (BTC) data, and the value of β decreased slowly with increasing flow velocity. Here, the data are reanalyzed with the full spectrum of ψ(t) gleaned from analytical calculations [Cortis A, Chen Y, Scher H, Berkowitz B. Quantitative characterization of pore-scale disorder effects on transport in “homogeneous” granular media. Phys Rev E 2004;10(70):041108. doi: 10.1103/PhysRevE.70.041108], numerical simulations [Bijeljic B, Blunt MJ. Pore-scale modeling and continuous time random walk analysis of dispersion in porous media. Water Resour Res 2006;42:W01202. doi: 10.1029/2005WR004578] and permeability fields [Di Donato G, Obi E-O, Blunt MJ. Anomalous transport in heterogeneous media demonstrated by streamline-based simulation. Geophys Res Lett 2003;30:1608–12s. doi: 10.1029/2003GL017196]. We represent the main features of the full spectrum of transition times with a truncated power law (TPL), ψ(t) ∼ (t₁ + t)^−1−βexp(−t/t₂), where t₁ and t₂ are the limits of the power law spectrum. An excellent fit to the entire BTC data set, including the changes in flow velocity, for each sandbox medium is obtained with a single set of values of t₁, β, t₂. The influence of the cutoff time t₂ is apparent even in the regime t < t₂. Significantly, we demonstrate that the previous apparent velocity dependence of β is a result of choosing a pure power law tail for ψ(t). The key is the change in the log–log slope of the TPL form of ψ(t) with a shifting observational time window caused by the change in the mean velocity. Hence, the use of the full spectrum of ψ(t) is not only necessary for the transition to Fickian behavior, but also to account for the dynamics of these laboratory observations of non-Fickian transport.  相似文献   

The solar occultation for ice experiment     

Larry L. Gordley  Mark E. Hervig  Chad Fish  James M. Russell  Scott Bailey  James Cook  Scott Hansen  Andrew Shumway  Greg Paxton  Lance Deaver  Tom Marshall  John Burton  Brian Magill  Chris Brown  Earl Thompson  John Kemp 《Journal of Atmospheric and Solar》2009,71(3-4):300-315

The Solar Occultation For Ice Experiment (SOFIE) was launched onboard the Aeronomy of Ice in the Mesosphere (AIM) satellite on 25 April 2007, and began science observations on 14 May 2007. SOFIE conducts solar occultation measurements in 16 spectral bands that are used to retrieve vertical profiles of temperature, O₃, H₂O, CO₂, CH₄, NO, and polar mesospheric cloud (PMC) extinction at wavelengths from 0.330 to 5.006 μm. SOFIE performs 15 sunset measurements at latitudes from 65° to 85°S and 15 sunrise measurements from 65° to 85°N each day. This work describes the SOFIE instrument, measurement approach, and retrieval results for the northern summer of 2007.  相似文献